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Section 4: Pollutant behaviour on field sites |
1 Hydrogeology Group, Department of Geological Sciences, University College London, London WC1E 6BT, UK
2 University of Bucharest, Faculty of Geology and Geophysics, Bucharest, Romania
The alluvial aquifer in Ploiesti, Romania, is severely contaminated with hydrocarbons. Petroleum products from four major refineries and 30 km of pipeline affect an area of 37 km2, occurring as free product floating on the shallow water table, dissolved hydrocarbon in the groundwater, and residual hydrocarbon in the unsaturated zone. Surveys performed between 1975 and 1995 defined the extent, nature and rapid movement of the contamination at rates up to 100 m a-1. Analysis of free product and soil samples showed a complex mixture of crude and refined hydrocarbons, with advanced biodegradation in both phases. Concentrations of non-volatile hydrocarbons in groundwater from the zone surrounding the free product plume were high, averaging 25 mg l-1, with dissolved contaminants as far as 6 km down-gradient of the industrial area. Organic and inorganic analyses indicate that biodegradation is occurring. Remediation requires the prevention of further spillages and application of economical and innovative technology. The highly permeable aquifer favours the use of in situ remediation, but remedial action is currently limited to a few skimming wells to remove free product.